Answer 2:
The Belousov-Zhabotsinsky oscillating
reaction was
discovered in the 1950s. Interestingly, it was
dismissed initially because the reaction
did not appear to go to equilibrium. It wasn't
until years later (early 1970s)that the reaction
mechanisms had been worked out. The details
of the BZ reaction is somewhat intricate, and I
will not try to describe all the details here (but
I'd encourage you to look into it yourself if
you're interested!).
There are basically three
processes, or groups of reactions that drive the
BZ reaction:
Process A: consumes bromide
ions
Process B: Cerium is oxidized
Process C: Cerium is reduced and bromide ions are
created.
Process B is an autocatalytic
process that oxidizes Cerium.
Autocatalysis means
that one of the products of the reaction is also a
catalyst for their action. In the BZ reaction,
this autocatalytic process is comprised of a
series of two reactions. Here, a product of the
first reaction drives the second reaction, and
then a product from the second reaction drives the
first reaction. This leads to a "circular
process" and the net result is a rapid formation
of one of the products.
The key to this
process is the concentration of the bromide ions.
When the bromide concentration is high, process A
is the dominant process. When the bromide
concentration is reduced past a "critical point,"
the autocatalytic process in B becomes dominant
and the Ce becomes oxidized. At some
point, process B will become limited and slow down,
such that process C kicks in. At this point, the Ce
is reduced, and bromide ions are generated. When
the bromide concentration reaches a certain point,
process A will start up again and whole thing can
begin again.
In this reaction, ferroin is
usually present as an indicator of the oxidation
state. As the oxidation state of Ce is increased,
the oxidation state of iron in the ferroin is also
increased and changes the color of the solution.
Thus as the processes go from A to B to C, and
then back to A, the color of the solution will
oscillate. While the color of the solution is
determined primarily by the oxidation state of the
Fe, there is probably also a contribution from the
Ce ions as well (although I'm not positive about
this). |