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Hi! Thank you for helping me with my previous
questions, I was wondering if you guys could give
me some insight on the following. We all
know that electrons create tighter bonds between,
or in, substances. Electrons are found in
electricity, as a matter of fact, electricity, or
an electric current, is basically a stream of
electrons. So when talking about something like
ionic or metallic bonds, if you were to pass an
electric current throught a substance, most
likely a metal like copper or metal foil or of
some other sort, would that significantly
increase the materials strenght? I have heard
that metallic bonds do contribute to somethings
strenght and many other things. If not, why? If
so, could the phenomenon be controlled, for
example, increasing or decreasing the additional
strenght of the material by increasing or
decreasing the electric current passing throught
it? How could I produce this phenomenon in a safe
experiment, how should it be designed? How
significant would the increase in strength be
given the metal, could I calculate that? Would I
get the same results as passing electricity
throught a material if I simply charged it with a
given amount of electricity/electrons? What metal
or other material would be the best to use? Is
there someother was I could increase a materials
strength besides this way?
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Question Date: 2008-02-16 | | Answer 1:
In general, just passing a current through a
metal will not change the strength of the metal.
Metals contain "extra" electrons that get shared
between the metal atoms, which are what causes
them to be so strong and such good conductors.
However, when there is a current running through a
metal, these electrons will still be there, just
moving very slowly. This probably would
not cause the strength of the material to change
very much, if at all. However, passing an
electrical current through a metal would probably
indirectly cause the strength of the metal to
decrease, due to the fact that the current will
cause the metal to heat up. When most materials
heat up, the bonds between the atoms can get
weaker; this will cause them to lose
strength. An experiment to test this would
not be too easy, since you would have to measure
the strength of the material at the same time as
you are running a current through it, which would
be rather difficult. Other way to possibly
change the strength of a material would be to heat
it up. As I mentioned earlier, heating the metal
will cause it to become less strong.
Additionally, if you heat the metal up, but then
very rapidly cool it back down (by dunking it in
cool water, for example), this could "lock in" the
positions of the atoms, and possibly make it even
stronger than it was to start. The only danger in
this would be to be very careful when heating the
metal up, since one could easily get
burned. Experiments to measure the strength
of the material can be tricky. Since metals form
such strong bonds, you would have to provide a lot
of force to the object in order to see how easily
it would break. However, if you used a smaller
amount of metal, then it wouldn't be quite so
strong to begin with, so it might be possible to
measure its strength. For example, if you used a
thin piece of metallic wire, you could hang
weights from it and see how much weight it would
take in order to break the wire. Then you could
heat the metal up and try it again while the metal
is still hot. Again, you'd want to be careful
here since the metal will be hot and could burn
you. After that, you could then try the method I
mentioned above of heating the metal and rapidly
cooling it and measuring its strength
again. There's a bit of information in this
answer, but I hope it helped out! | | Answer 2:
Passing current through or charging a typical
metal like copper will not significantly alter its
mechanical properties.In a metal, the Fermi level
of electrons, which you can think of as a kind of
average energy of electrons in the metal, is above
the conduction band edge. This means that
electrons are essentially shared throughout the
material because electrons in the conduction band
can respond freely to an applied electric field.
These conduction electrons are not bound to a
single atom, and adding charge to or subtracting
charge from the metal will only raise or lower the
Fermi level a bit. The conduction electrons do
not contribute to the bonds of the
atoms. You should find that if the current
density is high enough, the metal will become hot,
increase its resistance, and lose some of
itsstrength/rigidity. This is primarily a thermal
effect since largecurrent means electrons in the
metal scatter much more often and transfer kinetic
energy to heat energy. The atoms in the hot metal
move about more freely due to thermal energy, are
less ordered, and make the metal less rigid. The
metal also expands when heated. If you can find
very thin wires, you could measure these thermal
effects due to large current densities without
having to apply much voltage. You'd need a
multimeter and a means of applying tension to the
wire to test its breaking point. A thermometer
that you could clip to a point on the wire would
be nice as well. There are, however,
piezoelectric and thermoelectric materials which
do exhibit changes in material properties when one
applies a voltageindependent of resistive heating.
Piezoelectric expand or compress when a voltage
is applied, while thermoelectric materials acquire
a temperature gradient under an applied voltage.
These sorts of materials are used commercially in
many ways, but I am not sure if they are available
in a useful form for a science experiment. | | Answer 3:
What you are asking is basically the
fundamentals of atomic quantum
mechanics. Electrons are present in atoms in
what are called"orbitals", which are energy states
that electrons exist in as part of an atom's
structure. They are usually depicted graphically
as electrons orbiting the atomic nucleus, much the
same way that planets orbit a star. This isn't
actually true, however; electrons exist as a
probability wave distributed around the nucleus,
in which the probability of encountering the
electron at a given point in space is determined
by this wave. The lower the energy state of the
electron, the deeper the orbital and thus the more
energy required to strip the electron from its
atom. When two atoms bond together, the
electrons involved in the bonding form a new,
bonding orbital that exists between the atoms
being bonded. This orbital isat a lower energy
state, meaning that it requires more energy to
force the electrons out of it and break the bond.
This is why covalent bonds are strong and make
strong materials: the chemical bonds do not want
to break, because it would require a lot of energy
to pull the electrons out of their low-energy
orbitals. Electricity works like this:
electrons in a high energy state or otherwise
free, can leap from one atom to the next in the
direction of the cathode. The electron needs to
jump into an unoccupied orbital in the atom that
it is going to, but in doing so, it leaves its own
former orbital vacant, allowing another electron
to come in and fill it. Thus, salt water conducts
electricity well because it has ions that are
electrically charged and can migrate through the
fluid towards the appropriate electrode. Metal
conducts electricity because the outermost
electrons in a metal are in a semi-free state and
there are plenty of vacancies in the outer,
higher-energy orbitals that electrons can move in
and out of. Last, plasmas are good conductors of
electricity because the electrons have been
stripped completely off of their atoms by the heat
of the plasma, and consequently can go where they
will. Now, back to your question: what
experiments can you do that will demonstrate this?
I just said that heating causes electrons to
become loose, ultimately becoming free if you heat
it to the point where it ionizes and becomes a
plasma. You can't heat it that much safely, but
you certainly can heat substances and cause them
to lose their strength: for example, frozen cheese
isas hard as a rock, but if you heat it up, it
will melt. So, with that, here is the
experiment: choose a substance that has a low
melting point (as I said, cheese will do). Take
strips of this substance, and insert a weight into
one end of each strip, and add a hole to suspend
the other end of the strip from across bar, a
clothesline or something like that. After you have
made the holes and attached the weights, stick
some of your samples in the freezer, some in the
refrigerator, keep some at room temperature, and
heat some up in a Tupperware container that you
immerse in warm water. When you are ready to do
the experiment, attach them to your hanging line,
and record how much they sag, and how quickly.
Your hypothesis is that the ones you have heated
will have had their electrons loosened by the
heat, and so will not be as strong as the ones
that you froze. | | Answer 4:
Good questions! Let's back up a
bit... Electrons don't just create tighter
bonds between substances; they are the reason why
substances are held together. Every solid and
every molecule is held together by electrons. Or
to put it another way, electrons are what bond
atoms to each other. If an electron is
tightly bonded between two atoms, it can't move.
So it won't participate in electrical current,
because it's stuck. Only electrons which are not
tightly bonded can conduct electricity. We call
the bonded electrons valence electrons. Each
element has between 1 and 8 valence electrons.
Most of the time an atom will try to fill a
"shell" with 8 valence electrons, by using some of
its own and by bonding to (or sharing electrons
with) its neighbors. For example, oxygen has a
valence of 6, and hydrogen has a valence of 1. So
water (H-O-H) gives the oxygen atom in the middle
a total of 8 valence electrons, including 2 that
are shared with hydrogen. Valence electrons,
as I mentioned, usually don't conduct electricity,
because they're bonded. In metals, there are
additional electrons in each atom that are not
tightly bonded to the atom, and these are free to
move from one metal atom to the next. These
"metallic" electrons don't contribute
significantly to the strength of the material,
which is mostly determined by valence electrons.
So, passing current through a metal doesn't
significantly change its strength. There are
two common exceptions, though. The first is
temperature. The strength of many materials
changes with temperature, and passing current is
an easy way to increase temperature. There are
some materials called shape metals or shape memory
alloys which revert to their original shape when
you heat them up. The second exception is
semiconductors like silicon. In silicon, it's
possible to break a few of the bonds, which frees
a few of the valence electrons (like 0.0001% of
them). You can do this either by shining light on
the silicon, or by adding impurities to the
silicon which have extra electrons. Then the
silicon can conduct electricity. But the strength
of the silicon is not significantly reduced
because 99.9999% of the electrons are still
tightly bonded. If you wanted to test the
experiment, you could hang a milk jug from a ring,
and hang the ring from some very thin piano or
guitar wire, or some very fine steel wire, which
you can buy in small spools from a hardware store.
Wrap one end of the wire around a metal post
which is screwed into solid wood. Now using a
hose or watering pot, start filling the gallon jug
until the wire breaks. Keep track of how much
water you've put into the jug. Now, start over
with new wire, but this time you add connections
to a lantern battery (6V) or a stack of "D" size
batteries. Use heavy wire to connect from the
batteries to each end of the piano wire. (You can
buy wire with alligator clips on it at an
electronic store or hardware store.) Be careful,
because the piano wire will get very hot, so you
don't want to get burned, and you don't want it to
touch anything that would melt or catch fire. Now
with the wire hot, quickly fill the milk jug to
the same level and see if the wire breaks. If it
breaks sooner, then the wire has been made weaker
by heating. Anyway, that may be more than
you wanted to know, but hopefully it gives you
some ideas to play with! Click Here to return to the search form.
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