Answer 1:
Nitric acid is a powerful oxidizer as well as a
very strong and somewhat unstable acid. Any acid
works by donating Hydrogen to evolve water -- in
the case of Nitric acid, the metal causes the
nitric acid to break down into Hydrogen and
nitrate ions which then combine with the copper to
make copper nitrate, Nitrogen dioxide and water.
(If there is more water present initially, it is
broken up by nitric acid to make Hydronium
(H30+) and Hydroxide (OH-) ions
coordinated with the nitrate ions. In that case,
NO is produced instead of NO2 -- both
of these are poisonous gasses, indeed
NO2 can react with water to make more
NH03 -- a process that can happen in
your lungs if you inhale NO2.
(NO2 is one of the nastier by-products
of automobile operation-- and is closely monitored
by modern pollution controls). As to why
this happens, strong acids are very weakly bound
to their hydrogen and thus greatly accelerate the
corrosion process. (If you place copper in water,
it will also be attacked by the naturally
occurring H3O in the water -- leading
to Copper Hydroxide, but this process is very slow
unless there are substantial salts dissolved in
the water (they can react with the Copper
Hydroxide to make carbonates and other insoluble
salts-- like in old water pipes). An alternative
way to accelerate corrosion is electrolysis --
i.e. if you put a small amount of salt in water
and place two copper wires in the solution in
series with a battery, you can generate hydrogen
gas while the Chlorine produced will mostly attack
the copper to make cupric chloride
solution. Copper is often blue or green in
water-coordinated salts-- There is a very nice
demo on line to watch what happens at: demo The
deeper question you ask is "what are the actual
mechanisms of the action of the acid?" --this area
of study is termed "reaction dynamics or kinetics"
and is the subject of a great deal of current
research since tools to measure tiny quantities of
very short-lived ions have only become available
in the last 20 years or so. It is usually easy to
determine if a reaction is energetically
favorable, but much harder to determine reaction
rates, which depend on the detailed process-- a
good example is the action of Catalysts or Enzymes
which tremendously accelerate reaction rates,
without themselves being consumed in the reaction. |