Answer 1:
Water is a most unusual substance. A unique
aspect is that the solid form (ice) actually has a
LOWER density than the liquid form! This is why
ice floats. Most solids are denser than their
corresponding liquids at the same temperature and
pressure. This is not the case for
H2O. So if a can is filled with
ice and sealed the ice occupies some volume and
the pressure in side the can is fixed at some
value appropriate for the Temp conditions. Now as
the can and ice warms up, the ice melts and the
liquid OCCUPIES LESS VOLUME THAN THE ICE did. Now
since the pressure is inversely proportional to
the volume, the pressure INSIDE the sealed can
drops... when that happens, the outside the can
pressure is BIGGER than the inside the can
pressure and it is this pressure difference that
if it exceeds the strength of the can causes the
can to collapse. A similar effect can be
illustrated via the following experiment. put some
water in a coke can and bring the water inside the
can to boiling... the pressure in the can will be
equal to the pressure in the room with the
important difference that the pressure in the
steam of the can will be water pressure whereas in
the atmosphere the pressure is exerted by diatomic
oxygen and diatomic nitrogen. Now SEAL the can and
let it cool. ... As the steam cools in the can the
steam will condense back to liquid water (which
occupies less volume than steam)....and again if
the can is sealed the pressure inside will drop
below that outside and the can will spontaneously
crush itself. If you do this experiment at
home be careful. I would suggest heating the can
with water inside by put the can in a bigger pot
with water in IT so that you never heat the can
directly... then once the water inside the coke
can is boiling remove it, seal the can and and
let it cool. You should do this experiment when a
teacher or you mom o dad can watch because it can
be dangerous when playing with boiling water and
kitchen stoves. So you always have to
think of the consequences and dangers of any
experiments, be prepared to handle emergencies and
to always expect the unexpected. Many chemists
have lost their lives or been injured because they
let their guard down. |