Answer 1:
This is a very interesting question and we will
need to get into some detail to answer it, but I
think it will be worth the try.
Here is a
short answer: Because the change in the atomic
number implies an important change in the
structure of the elements, and the forces between
the atoms are therefore very different, when the
forces are huge you will have them solid and when
they are much less intense you will have them as
gases. But if you want to know the details of
this
situation, read on.
Let's begin by rephrasing
your question. Even if I perfectly understand what
you meant by "some elements are gas and others are
solid", I hope you will agree with me in adding
"at room temperature", because if you make the
temperature high enough, you will be able to
liquefy most and vaporize all of the
elements at
ambient pressure. So, in other words your question
could be stated: why the melting and boiling point
of the chemical elements varies so drastically as
we move along a the first period in the periodic
table? As you have correctly pointed out the
next neighbor has only one more proton... and that
makes a huge difference!!!
Taking the example of C
and N, (this statement can be generalized) I can
say that even one proton and electron more in the
atom can radically change the way the atoms can
establish links among themselves (in chemical
terms: form bonds) to show the different
forms of
pure elements at room temperature. We have to go
now down to the details of the electronic
structure so that you can better understand.
Carbon has an atomic number of 6, that means 6
protons in the nucleus and six electrons orbiting
around it. Those electrons are distributed into
the so called "electron shells". The six
electrons
of carbon go this way: two in the first shell and
four in the second shell. We call those in the
second shell "core electrons" and that
means they
are internal in the electron structure and not
ready to participate in the bonding of the atoms.
So we have four left. So the most stable form of
carbon is that where every carbon atom is
surrounded by other four carbon atoms and each
pair is sharing two electrons. In this ways all of
the atoms can count eight electrons in the second
shell and that is a very stable electronic
configuration. The solid thus formed is called
diamond and since the carbon-carbon
covalent bonds
are very strong and each atom is linked to four
other atoms, the whole crystal is extremely stable
and can be heated in the absence of air up to 3825
degree Celsius before it vaporizes.
Going to N (nitrogen), now
the outermost electrons are five. Since the atoms
want to have eight (the stable configuration),
every two atoms pair, sharing three electron pairs
(three covalent bonds) and they form the molecule
N2. The molecule itself is very stable,
that means
a lot of energy is needed to break those three
bonds. But the interaction among the N2
molecules
is relatively weak, the so called van der Waals
forces, and this way, N2 is a gas
at room
temperature and it will not liquefy until -196
degree Celsius.
Please note that not always
the change in one proton and electron produces
such a dramatic change in the electronic
properties. When you go to higher periods of the
periodic table, among the metallic elements,
variations are much smoother, again because of the
very similar electronic structure of the adjacent
elements that form very similar type of bond,
known as metallic bond.
2. Well, this one
if much tougher than the first one. The short
answer is: We scientists do not have yet a really
good explanation to this fact. All we know is that
the attractive forces between mercury atoms are
weaker that those in their neighbors. Since this
question is often asked by many students, in a
service similar to Scienceline offered by the
scientists at Argonne National Laboratory I found
a couple of interesting answers, please follow the
link to:
click here
Hope
to have helped you a little in getting a better
understanding of the wonderful universe in which
we live! Click Here to return to the search form.
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