Answer 1:
This is a good question. As you point out,
according to the ideal gas law (PV=nRT where
P=pressure, V=volume, n= amount such as moles,
R= the ideal gas constant, and T= absolute
temperature) when you cool a gas it contracts;
yet, as you also point out, when you put a can
of soda in the freezer it expands. This is
because when the water in the soda freezes, it
expands. Water is a very unique liquid in that
unlike most other liquids, the solid phase is
less dense than the liquid phase (this is why
ice floats). So, when you put a can of soda in
the freezer, the water in the soda freezes and
expands which causes the can to expand. The
reason water expands when you freeze it is
because water molecules are tetrahedrally shaped
and make up to four hydrogen bonds with the
neighboring water molecules (two hydrogen bonds
are donated and two are accepted). This forms a
network of solid water which is less dense then
the liquid phase where in some of the hydrogen
bonds have been melted and the water molecules
tumble around at a higher average density.
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