Answer 1:
Real heat engines transferring energy between
two reservoirs are less efficient than Carnot heat
engines. This is a consequence of the fact that
real heat engines undergo irreversible processes,
and irreversible processes are less efficient
(transfer less heat energy for a given
temperature). This in turn is because of the
second law of thermodynamics, which states that
the entropy of an isolated system is always
maximized (never decreases) at equilibrium. If an
isolated system undergoes an irreversible process,
it is being pushed out of equilibrium. The system
will maximize entropy in the process to get to its
equilibrium state, and thus entropy increases in a
system undergoing an irreversible process.
Mathematically for the heat engine, we say:
dS = -Qhot/Thot + Qcold/Tcold
work = -Qhot + Qcold
efficiency = |work|/Qhot
= |-Qhot + Qcold|/Qhot
= 1-Qcold/Qhot
(since work is negative)
now, since dSsystem = 0,
-Qhot/Thot + Qcold/Tcold = 0
which implies that
Qcold/Qhot = Tcold/Thot
efficiency = 1-Tcold/Thot
So the efficiency of your heat engine is
limited by the difference in the temperatures of
the reservoirs. I hope this helps.
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Answer 7:
That's a great question and a very advanced one
on the topic of thermodynamics. The short answer
to your question is no, the Carnot cycle is the
theoretical maximum efficiency of any heat engine,
ever. But let me explain why that is the case. So,
as you must already know, a heat engine produces
useful work by using the energy from some working
fluid (it could be air, water vapor, or any other
liquid or gas). Energy can come in two forms,
either heat or work. When we talk about work here,
what we mean in moving something with some amount
of force. A car's engine produces work by rotating
the wheels against the forces that tend to slow a
car down. For the heat engine to produce work, the
working fluid must be at some high temperature,
hence it has a lot of useful energy. The heat
engine then extracts the heat, turning it into
useful work (like spinning the shaft of a motor)
and then dumps out the working fluid to some
cooler source, called a sink (as in fluid is
sinking in). At the end of the cycle, the working
fluid cannot be cooler than the sink, because the
only way to cool the working fluid is for the sink
to absorb its heat. Since heat only flows from
high temperature things to low temperature things,
the working fluid will never get colder than the
sink. So basically, the energy available to the
heat engine is all the energy in the high
temperature working fluid. However, by necessity,
the working fluid has to come out at the same
temperature as the sink, and so when the working
fluid is dumped out, it takes with it some heat
energy. The efficiency of the cycle is defined as
the amount of useful work that you get out of the
system, divided by the amount of energy that you
put in originally. You originally put in all the
heat at the working fluid's high temperature
state. But the work you got out is only the
difference between the high temperature state and
the sink temperature, so you will never be able to
get better than that, and that is described by the
Carnot cycle.
But even the Carnot cycle is ambitious, it is a
theoretical cycle and will never, and can never
exist in real life. In real life there are always
losses, due to friction and imperfections. So the
theoretical max can never even be reached.
Let's look at some real life cycles, like the Otto
cycle, which is the principle on which a gasoline
car operates. The working fluid is air, taken from
outside, the high temperature is provided by the
fuel. (It also produces high pressure, but we can
ignore that for illustration purposes.) The high
temperature air expands, pushing on a piston,
which eventually drives the wheels, producing
useful work. When the air has pushed the cylinder
as much as it can, it is vented out as exhaust.
The outside air is the sink in this case. The air
can never be vented out at a temperature lower
than the outside (because it simply won't cool
down that much), and in fact, it is usually vented
at considerably higher temperature. Remember that
since heat is a form of energy, all the hot are
that comes out of the exhaust is just wasted
energy. Then new air comes in and the cycle is
repeated.
So, indeed, the Carnot cycle is the most efficient
cycle because it describes a situation in which
you can usefully use all of the energy contained
in the working fluid as it moves from high
temperature to sink temperature (low temp.), but
in reality it is impossible to actually do that.
For reasons why, you should look into entropy and
the second law of thermodynamics. Entropy is a big
subject, but it basically says that energy always
spreads out and becomes less useful. Entropy is
connected to all types of scientific questions,
from how the universe started to why time flows
forwards, and not backwards. It's an interesting
subject, but too much for this answer.
Thanks for the question.
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