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What will be the state of water if we freeze
further negative temperature below the ice state
limit? Could it exist as liquid again or stay
being solid ice?
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Question Date: 2014-06-13 | | Answer 1:
That's a very interesting question that is
unexpectedly nuanced at first glance. We are often
taught that water takes on three forms- as liquid,
solid, and vapor- and that you find these forms at
particular temperatures (i.e. ice below 0 degreed
C and vapor above 100 degrees C). But it turns out
that the state of water depends on both
temperature and pressure. The common temperatures
we know ice and vapor to form are only true for
atmospheric pressure, which is the pressure most
everyday things happen.
How do we know which phase water is?
People have figured out using thermodynamics the
dependence of phase (what you call the state of
water) on temperature and pressure, and put them
on graphs called phase diagrams. A phase diagram
for water can be found here. By picking a
particular temperature and pressure, you can
figure out what phase water is.
There are several key features in a phase
diagram. The lines, phase boundaries, that
separate the regions of ice, water, and vapor are
lines of two phase coexistence. That means at
temperatures and pressures along the boundary
between water and ice, both water and ice can be
found at the same time in equilibrium with each
other. Most of the time these phase boundaries
have positive slope. But water is quite special;
the phase boundary between water and ice is
slightly negative. This captures the fact that
water expands in volume slightly upon freezing.
The triple point is where all the phase boundaries
intersect and marks a special temperature and
pressure where all three phases exist in
equilibrium. There is also another interesting
point called the critical point. Pressures and
temperatures above this point result in an
alternate phase called a supercritical liquid
where liquid and gas are indistinguishable.
If you're further interested, there are also
phase diagrams for a whole multitude of materials,
such as multicomponent systems (e.g. mixtures of
elements or compounds, such as alloys). They
pretty interesting to look at (a good example here
of mixing silver and platinum), and predict how
things mix at different temperature. It's a whole
area of research and study!
Why is the phase dependent on temperature and
pressure?
A phase can be thought of as how much the species
can wiggle around and how well bonded adjacent
species are to each other. For example, solids
have closely packed species that rigidly vibrate
and gases have minimally interacting species that
whizz about. Temperature is equivalent to thermal
energy, so the higher the temperature, the more
energy the atom/molecules have to wiggle around.
Pressure does the opposite. The more pressure you
apply, the more you push together the atoms and
force them to be move rigidly. There are other
factors that I've left out, but that is the
general idea.
So in answer to the original question, you can
choose whatever phase you want water to be if you
choose the right temperature and pressure!
Hope this helps!
| | Answer 2:
Well, it turns out temperature isn't the only
thing that's important for determining the phase
of a compound; pressure is important as well.
This is what phase diagrams describe; for example,
the phase diagram of water is shown here: h2o
phase diagram
The point is that if you keep the pressure fixed
(at, say, atmospheric pressure), then once you
cool down water enough to freeze it, it will stay
frozen no matter how low you make the temperature.
However, water has the interesting property that
its frozen form is less dense than its solid form;
that means that if you take frozen water and
compress it while keeping its temperature
constant, you can force it to melt (you need a TON
of pressure to do this, though). You can even
lower the temperature as you do this, as long as
you increase the pressure fast enough.
So the short answer is that as you decrease the
temperature of a block of ice, it will remain ice,
unless you also subject it to very, very high
pressures.
| | Answer 3:
Great question! Assuming that the pressure of the
system were to remain constant throughout this
cooling process, water would remain as ice no
matter how cold we lowered the temperature.
Interestingly, if we were a bit below freezing
temperature at 0 °C and we started to lower the
pressure, at some low enough pressure the ice
would sublime straight into a gas (without passing
through a liquid phase). Scientists study this
interesting phase behavior of water and other
substances, and map out a temperature versus
pressure diagram, called the phase diagram.
| | Answer 4:
If you continue to decrease the temperature, water
will always continue to be solid ice. However, ice
turns out to be much more complicated than you
might expect, and depending on the pressure, you
can have many different forms of ice. Depending on
the pressure, different structures of ice become
stable, so there can be phase changes. However,
there have been no experiments that have shown
solid ice transforming to a liquid when it is
cooled further.
| | Answer 5:
At temperatures below the freezing point water
will stay in solid phase as ice. You can see from
the phase diagram for water in Answer #2
(from page:
equilibria
phase rule). This shows the phase of water
versus both temperature and pressure, at pressures
of 1 atmosphere (standard air pressure around us)
water will be solid below 0 degrees Celsius.
| | Answer 6:
I'm not sure exactly what you mean by the ice
state limit, so I'll do my best to explain this
with the graph in Answer #2.
click
here
On the y-axis is pressure. 1atm is standard
pressure, so along the 1 atm line, you can see
that as temperature (x-axis) increases, ice
becomes liquid water (at 0C), and liquid water
becomes water vapor (at 100C). If you keep ice
cooling even further it remains solid ice all the
way down (staying along the 1atm pressure
line--changing increasing or decreasing the
pressure a lot may change this as shown on the
graph).
The bottom line is that ice stays ice as you
continue to decrease temperatures into the
negative C, and will not turn back into water at
constant pressures. Interestingly, the crystal
structure of ice can change though, based on the
pressure. That means essentially that the
molecules pack in different shapes. Typical ice
that we see is always ice-1, but under extreme
pressures, the packing of the molecules can change
to make ice-2, ice-3 etc. If you've ever read Kurt
Vonnegut's book Cat's Cradle, it talks about an
ice-9. There IS an ice-9, but it only exists at
remarkably high pressures and doesn't act the way
it does in the book. But, it's an interesting bit
of science fiction (and a great novel too).
| | Answer 7:
At atmospheric pressure, (pure) water below 0
Celsius will be either remain a solid or sublime
and become a gas, not a liquid. Liquid water can
exist at lower temperature, but only at higher
pressure than at the surface of the Earth (or if
it contains salt or other solutes).
| | Answer 8:
t is possible to supercool liquid water so that
it still exists as a liquid even though it is at a
temperature where the solid state of water (ice)
is stable. This supercooled liquid state is what
is known as a metastable state. At temperatures
below freezing point, the solid state is
thermodynamically stable (lower in free energy)
than the supercooled state. However, the system
can be kinetically trapped in this metastable
state.
To supercool water, you can take distilled or
purified water in an unopened water bottle
(impurities can serve as nucleation sites for
solid ice formation, so we want to avoid these).
Cool the water in a freezer for several hours, and
then carefully remove the bottle from the freeze.
If the water inside is already solid, then you
will have to re-do this cooling process. To get it
to crystallize (form solid ice) from the
supercooled state, you can shake the bottle or
pour it over ice.
| | Answer 9:
The temperature vs. pressure phase diagram of
water shows us that at about 1 atmosphere of
pressure (which is nearly equal to the ambient
pressure at sea level) liquid water turns into
ice. As we continue to lower the temperature
though, there isn't much apparent change according
to a simple phase diagram. Our ice will stay ice
as we cool.
Now, there are ways to keep water a liquid
below 0oC at room temperature while still
maintaining the same pressure. You could add an
impurity like salt. Salt is often used on roadways
to keep ice from freezing and making the ice
slippery.
You could also have "supercooled" water. To
turn into ice, the liquid water needs a nucleation
point. The nucleation point is just something that
ice crystals can start growing on. If there's no
"seed" for the ice crystals to grow, they will
just stay as a liquid. As soon as a particle of
dust is added or the container is shaken, the
water, which can be much lower than 0oC, will
nearly instantly freeze. You can supercool water
yourself, but it's a very delicate process. The
easiest way would be to take an unopened bottle of
purified or distilled water and stick it in the
freezer. In a few hours, the temperature will be
below freezing, but the water will still be a
liquid!
You could also increase the pressure. You might
notice something interesting to the phase diagram
of water compared to other materials. As the
pressure is increased, the melting point
decreases. This may seem strange, but without
this, life would be much, much different (or even
non-existent!). That means you could increase the
pressure and have ice turn into water even as you
lower the temperature below 0oC. Food scientists
have applied this principle to thawing: thawing
with high pressures can thaw food nearly three
times faster than at normal atmospheric pressure.
One interesting tidbit that the water phase
diagram does not point out is all of the different
crystal rearrangements of water. Hydrogen and
oxygen have a little bit of freedom to distort
their bonds and change the crystal shape. There is
a lot of research on finding new rearrangements of
water and exploring their properties. Researchers
call these rearrangements "polymorphs" (which
literally just means "many shapes"). If you're
familiar with Kurt Vonnegut's Cat's Cradle, he
writes about a fictional form of ice that freezes
at room temperature. If you seeded water on Earth
with this ice, all water would immediately freeze
solid at room temperature and could destroy all
life! Fortunately, there aren't any forms of ice
like Vonnegut's creation, but there have been as
many as nineteen different polymorphs of ice
discovered thus far! Click Here to return to the search form.
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