Answer 1:
That's a great question! You have touched upon
a huge area of study of materials science, of
which the answer might surprise you. Crystals may
be found everywhere, and so have any application
conceivable.
In materials science, what constitutes a
crystal is much more general than perhaps what one
thinks of at first. A crystal is any
material exhibiting long-range order.
To describe the crystal structure mathematically,
you need a lattice (an arrangement of spots to
fill in space that have long range order) and a
basis (the things that fill the lattice sites,
such as atoms). Most generally, this looks like
the diagram here click
here, please
In which the atoms fill in the spots designated
by the lattice. The lattice and basis can become
complicated quickly, but we'll stick with the
basic examples. You can further describe a crystal
structure with a unit cell and basis
vectors.
A unit cell is a small chunk of atoms
that when translated can reproduce the crystal
structure. Two examples are shown in the
colored boxes. The directions that you translate
the unit cell are the basis vectors. As you can
see, the definition of the unit cell is not
unique.
It turns out, most materials are
crystalline. Even metals! (I did not know this
in 10th grade, and this literally blew my mind.)
Metals exhibit a variety crystal structures,
such as body-centered cubic and face centered
cubic. These are basically names for how the atoms
pack together. There are definitely many uses of
metals and metal alloys, such as steel and bronze.
What are a few you can name?
In fact, there is a whole area of study for the
kinds of crystal structures possible. In general,
crystal structures follow one of 14 lattices,
known as Bravais lattices. Wikipedia has a
pretty great article about crystal structure:
read
in this link .
There's even a whole branch of mathematics that
is used to describe crystal structures, known as
group theory.
Most elements exhibit a crystalline structure
at equilibrium. Perhaps most notable is silicon,
which has the diamond face centered cubic structure:
cubic
structure.
Crystalline silicon, as you may know, is used
in pretty much every electronic device ever, such
as transistors, lasers, integrated circuits, and
solar cells.
This also extends to research on materials that
people are studying to replace silicon. This is
still a very active area of research. For example,
in the research for my lab group, we study
electronic and optical properties of metal oxides
and nitrides using first-principles
calculations/simulations. Because modeling a real
solid with 1026 atoms is extremely
difficult to do mathematically, we use the concept
of the unit cell in crystals in our research on a
daily basis to simplify the math.
From our research, we can explain and make
predictions on a variety of material properties
that are useful in applications ranging from
LEDs to transistors to smart windows to
even quantum computing!
The possible number of crystal structures is huge
and can become quite complex. One example is shown
on the link for a new material,
Li9V3P(8-x)O(29-x)
being studied for rechargeable Li-ion batteries click
here to see.
Every yellow triangle and blue octahedra
correspond to a group of atoms. This would be a
nightmare to draw by hand, but luckily there are
programs that can do it for you.
Other examples of uses of crystals also extend to
beyond the inorganic examples shown so far. For
example, the crystalline structure of proteins is
heavily studied in biology click
here to see example.
Proteins are extremely important for all kinds
of cell functions, and understanding the structure
allows researchers to understand how they function
and interact with their environment. All the
colored ribbons correspond to different chains of
proteins. As per the definition of a crystal, can
you deduce what the repeated unit cell would be?
But what does it mean to not be
crystalline?
It means to not have long-range order. One
common case is the amorphous phase, in
which only short-range order is present. You are
very familiar with an everyday amorphous material
- window glass (silicon dioxide)!. A
diagram of the structure of amorphous glass is
shown
here.
As you can see, there isn't the long range order
that is present in the crystalline phase. However,
locally, each Si atom looks just like it
does in the crystalline phase. The only thing that
is different are the bond angles and degree of
bonding that occurs (i.e., not every oxygen is
bonded to two Si, as found in the
crystalline phase). For this reason, amorphous
solids tend to have a lower density than
crystalline ones.
In order to obtain the amorphous phase, one
generally has heat up their material past the
critical temperature and quench it (i.e., cool it
very quickly). The most important part is the
quenching. When materials are in their
liquid state, there is no semblance of crystalline
order (think of the different between water and
ice), so if you freeze this lack of crystalline
structure quickly, you can obtain the amorphous
phase.
There are also not quite crystalline phases
that have been found. An important electronic
device example is the liquid crystal (e.g., liquid
crystal displays, LCDs). Although LCDs have
advanced quite a bit, its basic functionality can
be captured with the display on your calculator or
watch. The question is, how can you modulate the
screen pixels to be selectively black? The
engineered answer is liquid crystals. A liquid
crystal is a material that exhibits both liquid
and crystalline behavior. They are generally
composed of long and rigid hydrocarbon chains such
that these chains line up in an ordered fashion
over a long range (like a crystal!), but because
these chains are not strongly bonded to each
other, it can flow like a liquid. To get a pixel,
you sandwich some liquid crystal material between
two polarizers that are at right angles, and you
hook it to an external circuit. Polarizers filter
light and only let light going in one direction to
go through; when two polarizers are at right
angles, no light passes through. What
happens?
Follow this
link to find out!
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