Answer 1:
A good question! Batteries are an extremely
important technology and come in all
shapes and sizes They do not need power per
se, so much as they provide power. And this has
much to do with chemistry and materials
science. Although there many types of
batteries (so many that I could not do them
justice), they all work using a similar premise.
A battery is any device that converts
chemical energy into electrical energy. You
may have learned in your science classes that
matter is made of atoms composed of protons,
neutrons, and electrons. We are primarily
interested in electrons as it is (moving)
electrons that give you current (i.e., electrical
energy, plus or minus a few unit conversions).
Associated with each element is a characteristic
potential. (Strictly speaking, this is a potential
difference, with the zero potential taken to be
hydrogen by convention. You will learn in future
Physics classes that it is the difference in
potential energies that really matters.) This
potential energy can be thought of as the
amount of energy stored in your material that can
be used to do something. For example, holding
a ball above the ground gives it potential energy
(i.e., energy to fall via gravity). Voltage is
defined as the amount of energy (potential) per
unit charge.
The three major parts of any battery are the anode
(-), cathode (+), and electrolyte (liquid or
solid). The simplest of batteries that I first
learned are more generally called
electrochemical cells What happens is an
exchange of electrons called a redox reaction
(short for reduction and oxidation).
Reduction means you gain electrons; oxidation
means you lose electrons. This redox reaction
induces a current. Let's look at an
example
Shown here is an
electrochemical cell with zinc (Zn) and
copper (Cu), two classic materials to choose.
Because zinc loses its electrons easier than
copper (i.e., has a higher relative potential),
these electrons will flow towards copper when the
two materials are connected. This flow of
electrons is a current that can power something
like a light bulb. Notice that the chunks of zinc
and copper are in an electrolyte solution with
sulfate. This is what is known as a "salt bridge"
and keeps the zinc and copper charge neutral. This
system is relatively simple to make- you literally
just need some beakers, a chunk of zinc and
copper, some wires, and a light bulb.
So now you may ask, why aren't all batteries just
zinc and copper? It turns out that different
materials make better combinations. Lots of people
have worked on finding such new materials and the
technology behind batteries has evolved
substantially since the development of
electrochemical cells.
Perhaps you are most familiar with lithium-ion
batteries. These were a pretty exciting
technology, as lithium-ion batteries were
rechargeable with high energy density, could be
discharged/charged many times, and had slow loss
of charge when not being used. The difference
between a Li-ion battery and electrochemical cell
(apart from using solid materials instead of
solutions) is that instead of electrons moving about,
it is lithium ions Li+. In order for lithium ions
to be the carrier for the charge, the anode and
cathode need to have lithium in them.
For example,
lithium cobalt oxide (LiCoO2) is used
for the
cathode. If you look at the
crystal structure of
LiCoO2, you'll notice that the lithium
(in purple)
between layers looks pretty easy to take out and
put in. And indeed it is!
Developing better batteries is still very much a
huge active area of research. What goes inside a
battery can be pretty much anything! As materials
scientists, we are always looking for new
materials that can store more charge,
discharge/charge for many cycles, and last a long
time when not used. What are some examples? We
have seen examples of metal electrodes and
materials that involve more complicated
structures. But pretty much any set of materials
that can undergo a redox reaction of sorts could
act as a battery. In fact, just two days ago I
learned that there is research to use bacteria
(albeit in fuel cells- similar to batteries but
uses a constant stream of fuel instead) as a means
of harvesting electrical energy!
Hope this helps!
Best,
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