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Suppose a tank of carbon gas in a hospital has a
leak. Will the gas be found near the floor or near
the ceiling? Why? |
Question Date: 2016-05-19 | | Answer 1:
Compressed carbon dioxide gas is sometimes used
as a coolant, but usually carbon dioxide is kept
in solid blocks (known as “dry ice”). These
solid blocks of carbon dioxide sublime to gas at
-78°C, remaining at this temperature until they
completely evaporate. There are some advantages to
keeping it as a compressed gas, though – it can be
kept at room temperature in self-contained and
easily-filled tanks.
Let’s suppose a large tank of carbon dioxide
began to leak. The gas is kept at high pressure,
compressing it into a much smaller space. As the
gas leaks from the container, it rapidly expands
and thus cools. No matter where the leak began,
the leaking gas would drift to the floor,
since it is cooler than the air around it. But, as
it warmed up, would the carbon dioxide stay
near the floor? To answer that, we need to
know the density of carbon dioxide (1.84
kg/m3) and air (1.20 kg/m3)
at room temperature.
Since carbon dioxide is roughly 1.67 times
denser than air, it would stay near the bottom of
the room, although it would mix more as it reached
room temperature. In fact, very few gasses are
lighter then air when they are at the same
temperature – ammonia, methane, neon, hydrogen and
helium are lighter, while nitrogen is only
slightly (3%) less dense.
Did you know that a carbon dioxide leak
could be a fire hazard? Carbon dioxide itself
is not flammable and is actually used in some fire
extinguishers to suffocate flames (particularly in
commercial kitchens). So where’s the
danger? When such a leak occurs in an enclosed
space, the cold gas sinks to the floor and pushes
warmer air up to the ceiling, compressing it. This
can increase the concentration of oxygen past its
flashpoint so that an electrical spark near the
ceiling (say in the lighting fixtures) could cause
a fire, when it otherwise wouldn’t have. This is
why rooms designed to store compressed gasses
(even inert ones like nitrogen) are well
ventilated or fitted with oxygen sensors near the
floor to detect any leak quickly before it can
reach dangerous levels. | | Answer 2:
Carbon actually doesn't exist as a gas at room
temperature, so that one's easy--it would be solid
and on the floor! Maybe you're thinking of
carbon dioxide (CO2), which is a gas at
room temperature. This gas is denser (~2.0
kg/m3) than air (~1.2 kg/m3)
so it will pool near the floor. You can look up
the densities online to see that this is true.
An approximation that also usually works pretty
well is to consider the molecular weight of the
gas and compare it to nitrogen gas
(N2), since that is the biggest
component in air (78%). CO2 has a
weight of 12+16+16=44 amu ("atomic mass units")
for the carbon and two oxygens. Nitrogen has
14+14=28 amu. So you can see that one molecule of
CO2 is heavier than one molecule of
N2, which means it's heavier and it
will sink in comparison.
| | Answer 3:
All forms of pure carbon, including graphite
(found in pencils) and diamond are solids at room
temperature.
If a tank of carbon dioxide gas were
leaking, the gas would end up near the floor.
This is because CO2 is more dense than
air (about 2.0 kg/m3 for CO2
compared to about 1.2 kg/m3 for air, at
a typical temperature and pressure).
If the tank instead contained carbon monoxide
gas, the gas would be found throughout the
room. This is because CO gas is about the same
density as air. (Of course, this isn't
likely--hospitals have no reason to stock carbon
monoxide, which is toxic.)
Dense fluids settle to the bottom--this is a very
general rule. For example, it also explains why
hot air rises: gases become less dense when heated.
| | Answer 4:
That's quite an entertaining question. It
would depend on how heavy the carbon gas was. Gas
cylinders with carbon in them could be methane
[CH4] or carbon dioxide
[CO2] or acetylene for welding
[C2H2] or propane
[C3H8] or butane
[C4H10], both used for
heating.
If the gas is heavier than air, it will
sink. If the gas is lighter than air, it will
rise. That's why helium balloons rise,
because helium is lighter than air.
Air is 80% nitrogen [N2]. Its
molecular weight on earth is 14x2 = 28. Helium's
molecular weight on earth is 4. Carbon is 12.
Hydrogen is 1. Oxygen is 16. So you can
calculate the molecular weights of the different
carbon gases.
Also, the air in the room will be mixing, so
the gas will never be totally separated from the
air. Butane [C4H10] and
carbon dioxide are the heaviest ones listed, so
they'd be lying near the floor more than the
others, but the air would be moving, so they'd be
mixing around.
Best wishes,
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