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What happens when you let sugar dissolve in kool-aid?
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Question Date: 2018-11-06 | | Answer 1:
Like any dissolution process, dissolving
sugar in Kool-Aid results in a
solution, i.e. a homogeneous mixture of
two or more substances. (Also note that a
solution is special type of mixture, one whose
constituents cannot be differentiated by
sight.) The substance which makes up most of
the solution (here this is the Kool-Aid) is called
the solvent, and the substance(s) which
dissolve are called solutes.
During
dissolution, the bonds between particles of
the solute are broken and the particles are
distributed throughout the solvent. In the case of
sugar, the solute particles are molecules, and the
solvent is water (Kool-Aid is basically some stuff
dissolved in a large amount of water already). The
intermolecular bonds keeping the sugar
molecules next to each other are overcome in favor
of formation of bonds between sugar molecules and
water molecules (
schematic picture ). Note that the sugar
molecules remain intact; the bonds between atoms
in the molecules are not broken during
dissolution.
(As an aside, the "formula unit" of the
solute does not necessarily stay together. In
dissolving ionic compounds, the positive and
negative ions are separated (
dissociation ). Consider dissolving table
salt in water, an ionic compound comprising
positive Na+ ions attracted to negative Cl- ions.
Such a solution will contain Na+ ions bonded to
water molecules and negative Cl- ions bonded to
water molecules, but not the neutral (NaCl) unit.)
For more advanced students:
So far, the discussion has ignored any of the
chemistry and thermodynamics behind the formation
of solutions. This is an
extensive topic
in itself, but here is a brief overview.
To
form a solution, the energy of the solution must
be less than that of the separated solvent and
solute. If performing this mixing without special
equipment, our environmental conditions will be
those of isothermal mixing and constant
pressure,
and the energy change (dG) given by
dG_mix =
dH_mix - T*dS_mix
(T = temperature).
There are
two contributions to the energy change:
(i) dH = change in enthalpy, which is
energy due to
bonding, and
(ii) dS = entropy, energy related to
the number of arrangements of the particles.
Bonds
between solvent and solute particles can be either
more or less favorable (i.e. lower or higher in
energy) than solvent/solvent and solute/solute
bonds. If lower in energy (dH_mix < 0), then
solution formation will be favored; if higher in
energy (dH_mix > 0), then formation of a
solution
will be disfavored and the second component, from
entropy, will need to be larger to form a
solution.
Entropy is a tricky concept, but here it can be
considered to be related to the number of
arrangements of particles. When the solvent and
solute are on their own, separated and pure, each
has only one configuration (think, each particle
of solvent or solute can only be surrounded by
other particles of solvent or solute). After
combining them, there are many other
configurations (in very simplified example, say 1
solvent molecule next to 5 solvent molecules and 1
solute, or next to 3 solvents and 3 solutes,
etc.). Thus, the entropy of the system increases
by mixing and (because of the negative sign in the
dG equation) system energy decreases.
There is far more to be said, but this answer
can't include a full thermodynamics course. For
more information, see this
video
series .
| | Answer 2:
Let’s assume that there is a lot more Kool-Aid
than sugar in a glass. Kool-Aid
itself is actually a mixture of sugar, water, dye,
and flavoring. So when we add
our sugar crystals, the water molecules and sugar
molecules in the Kool-Aid
will come in contact with the surface of our
pure sugar crystals. Since sugar
molecules and water molecules are attracted to
each other, the water
molecules will slowly begin to pull away sugar
molecules at the surface of the
sugar crystals. Molecules of sugar that are
carried away will bounce around
with the water molecules and already-dissolved
sugar molecules in our
container. Eventually, the water and sugar
molecules will completely mix into
what is called a homogeneous solution - a
solution which has a constant
concentration of sugar and water at every point in
the solution. It is at this point
that you will no longer be able to see individual
crystals of sugar in the glass.
I said earlier that we assumed there was more
Kool-aid than sugar. This is
because the sugar can only dissolve in water if
there are enough water
molecules to surround the sugar molecules.
Once there are too many sugar
molecules and not enough water molecules, sugar
stops dissolving. This is
called the limit of solubility.
| | Answer 3:
A sugar molecule consists of a line or ring of
carbon atoms connected to alcohol
(oxygen-hydrogen) groups with one alcohol group on
each carbon. Oxygen exerts more of a pull on the
electrons in a water molecule than hydrogen does,
which causes the oxygen to accumulate negative
electric charge while the hydrogens accumulate
positive charge, creating an electrically-aligned
molecule called a dipole. Alcohol groups
in sugars
behave the same way, because they are made of the
same two elements as water. When a crystal of
sugar is placed into water (Kool-Aid is mostly
water), the oxygens in the water begin interacting
with the hydrogens in the sugar, and the hydrogens
in the water interact with the oxygens in the
sugar. This weakens and removes the
interactions
between the sugar molecules with the other sugar
molecules in the sugar crystal. As the sugar
molecules are pulled away from the crystal, the
crystal dissolves, leaving the sugar in solution
instead of in its solid, crystalline, state.
| | Answer 4:
Since Kool-Aid is mostly water, the sugar would
most likely dissolve without changing the Kool-Aid
much, except for making it sweeter. However,
continuing to add sugar into the Kool-Aid would
eventually result in what we call
"saturation", where no more sugar will
dissolve in the solution. At this point, any more
sugar that is added will simply sit at the bottom
of the liquid if no stirring is happening. | | Answer 5:
Fascinating question! Before I answer, I want
to briefly touch on how Kool-Aid mix works.
Kool-Aid is a flavored drink mix powder that is
added to water to make a liquid concentrate. Its
main ingredient are sugar and fructose, another
type of sugar found in fruits and vegetables. Next
is citric acid, a sour flavoring agent from
citrus, followed by ascorbic acid, another name
for vitamin C. There is also calcium phosphate,
like a calcium supplement, that acts as a
preservative. After those, the rest of the
ingredients are mainly artificial flavors and
artificial colors. Overall, this is a simple
ingredient list.
The fascinating part of Kool-Aid to me is that
despite sugar products making up the first two
main ingredients, Kool-Aid typically is
"unsweetened." This means that despite
sugar in the ingredients, the container still asks
for more sugar to be added. Which leads to your
question about what happens when that sugar
dissolves in the Kool-Aid and water mix. The
Kool-Aid mix and sugar added to water creates a
solution, or a mixtures where two or more
substances are well mixed or homogeneous. In this
case, the Kool-Aid and sugar are the
solutes dissolved in the liquid water, the
solvent. But you should know that liquids
can also be dissolved in other liquids, solids can
be dissolved in solids, and gases can be dissolved
in liquids.
Sugar is a polar molecule, meaning there
are places on its molecule structure where it is
slightly more positive and places where it is
slightly more negative. These two areas attract
one another, and because there are many of these
areas and the molecule is somewhat large, the
sugar is a solid. Water is also a polar
molecule. In water, the positive and negative
areas have a stronger attraction than the
attraction of the sugar molecules, causing the
sugar to dissolve. Energy is also required to
help break the bonds that keep sugar solid. I
will not go into details except to say that some
of that energy comes from the attraction of the
water molecules to the sugar molecules. You can
think of this as being similar to how you can
cross the monkey bars by holding tightly to the
bars, but Earth's gravity will always pull you
down to Earth's surface the moment your grip
weakens. This is why things like sugar and salt
will dissolve in water but sand will not dissolve,
because the molecules in sand are more tightly
bonded than the strength of the attraction of
water.
So as you add sugar to your Kool-Aid and water
mix, the sugar and Kool-Aid mix both dissolve into
the water.
I will close with saying that there is a limit
to how much sugar can dissolve in water. Higher
temperature water usually increases the amount
of sugar that can dissolve, while cooler
temperature water usually decreases the amount
of sugar that can dissolve. So you can actually
reverse the process of dissolving sugar. If you
dissolved sugar in hot water until no more sugar
was dissolving, then carefully cooled the water
without stirring it, the sugar will remain
dissolved in the water. However, if you had
dropped a few grains of solid sugar crystals into
the water solution at that moment, those sugar
crystals would have started to grow into larger
crystals, thus turning the dissolved sugar back
into a solid form. This process as how rock
candy is made. The dissolved solution can also
be turned back into solid sugar if the water is
evaporated. The water will be removed into the
air, and the remnants in the glass will be sugar.
This process is called a physical change.
The physical form of the sugar is changed, but
its chemical composition is not changed.
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