Answer 1:
The burning of a metal is essentially the
same as burning of any other material.
Burning
is simply two atoms or molecules
combining and releasing energy. This is
exactly what happens when a metal burns - the
atoms of the metal form bonds with the atoms of
the other species and release energy in the form
of light and heat. For example, the burning of
magnesium and oxygen is given by the
chemical equation:
2 * Mg + O2 -> 2 * MgO.
The products of burning metals are
ionic compounds, meaning that the reaction
has resulted in electrons being
removed from the metal atoms and transferred
to O atoms. For the magnesium example,
Mg(2+) and
O (2-) ions are produced (numbers in
parentheses
are charge values). The opposite signs of the
charges on these ions hold them together, similar
to the attraction between opposite poles of
magnets. This is not the case for all "burning"
reactions though. As one example, burning of
hydrogen (2 * H2 + O2 -> 2 *
H2O) produces a compound
with covalent bonds, meaning electrons
are shared
between the hydrogen and oxygen in the
H2O. (More
details on the differences in these bonds
here ).
Typically the word "burning" means that the
reaction involves oxygen in the form
O2. This is
not a requirement though; other molecules can
provide the oxygen, such as in the
reaction
of Mg with CO2 (watch the
video, it is great!), or iron oxide (rust)
providing the oxygen during reaction with aluminum
(a thermite reaction). Depending on how one takes
"burning", the reaction may not even require
oxygen. When hot enough, magnesium will react with
nitrogen to form Mg3 N2.
(Recall that the
atmosphere is ~78% N2. Thus,
burning
of magnesium in air will produce this
compound as well as the oxide.)
[Only semi-related, but perhaps
interesting] The
reason a metal can burn is the same as the
reason any other chemical reaction takes place:
doing so rearranges the electrons such that the
energy of the system is lowered. Burning of
metals produces very high temperatures, meaning
that a large amount of energy is released. This
indicates that the energy of the metal/oxygen
system can be greatly reduced by the two
reacting. Given that there is such a large
reduction in energy from burning a metal, one
might then ask why metals do not ignite easily. As
explained in detail
here, this is a combination of:
(i) inability of oxygen to reach most of
the metal atoms (atoms of the metal don't separate
from the bulk as readily
as other fuels);
(ii) the energy to break bonds
between metal atoms is high (this is part of the
cause of point (i) as well), so higher
temperatures are needed to start the reaction than
in burning of other materials; and
(iii) metals have high thermal
conductivity, so any heat that
is added is readily spread throughout the object,
thereby preventing sufficient buildup of
temperature to cause ignition (see point (ii)).
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Answer 2:
The metal atoms combine with a nonmetal (usually
oxygen, since that's what's in the air) to
create a salt.
To make a salt, the metal atoms give up some
electrons to the nonmetal. This means that
the nonmetal atoms fill their electron shells
while the metal atoms are stripped of their outer
electron shells. This releases energy, which is
why salts are stable. The energy is given off
as heat.
Note that the common salt on your table is made
of the metal sodium and the nonmetal chlorine.
The Earth's atmosphere does not contain much
chlorine, so burning a metal like sodium in
Earth's atmosphere will not create table salt (it
will create sodium oxide instead of sodium
chloride). To make table salt by burning sodium,
you would need to burn the sodium in a chlorine
atmosphere instead of an oxygen atmosphere.
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