Answer 1:
It sounds like you're doing some interesting
work on the iodine clock reaction. As I
understand it, there are several variations of the
iodine clock reaction. However, I think they
basically all come down to a slow reaction that
forms triiodide ions in the presence of an
acid, and a fast reaction where triiodide ions are
converted back to iodine ions in the presence of
thiosulfate (or bisulfate, I think works
too). When all the thiosulfate is used up, then
the iodine, and react with the start to form a
complex giving the solution its color. Now, I
don't know that much about iodine-alcohol
complexes, but I'll try to note a few things that
I would think about.
Iodine can form complexes with at least some
alcohols. One example would be with polyvinyl
alcohol - it forms a bluish / purplish complex
with iodine. Depending on what acid and what
alcohols you're using, I can imagine several
potential situations. If the concentration of
hydrogen ions (acid) decreases, then the formation
of the triiodide ions would probably be somewhat
inhibited. However, this wouldn't really change
the colors that are obtained, but rather the rate
at which the color changes. If you're seeing
radically different colors, then you may want to
look at possible reactions between your acid and
alcohol, and how those products may or may not
react to form iodine complexes.
Unfortunately, I don't think I can help you
much more beyond this. In addition to looking up
information on the iodine clock reaction, you may
also want to look at the Briggs-Rauscher
oscillating reaction, which is similar, but
involves more chemicals and different color
changes. |
Answer 2:
That's a fun experiment, isn't it? I
don't have any useful advice about this specific
experiment, because I hadn't heard about the
alcohol effects, but I'd suggest a search on
www.google.com for iodine starch alcohol.
I'm too busy, or I'd do the search myself. If the
experiment is the one I know about, then you're
watching saliva degrade starch? So the
alcohol probably denatures (kills) the enzyme in
the saliva? You could test that hypothesis by
incubating the saliva for a while with vs
without alcohol and checking the iodine-starch
reaction for the 2 different saliva treatments.
Good luck with your research. Click Here to return to the search form.
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